What is the difference between an acid and a base?

An acid is a substance that releases hydrogen ions (H+H^+) when dissolved in water, while a base is a substance that accepts those hydrogen ions. In the most common definition used in chemistry, you can simply think of acids as "proton donors" and bases as "proton acceptors."

Imagine a game of catch. The person throwing the baseball is like an acid donating a proton, while the person catching the ball is like a base accepting it. In chemistry, that "ball" is a tiny hydrogen ion, and passing it back and forth is exactly what drives acid-base reactions.

Two Ways to Define Them

Chemists use a couple of definitions to describe acids and bases. The simplest is the Arrhenius definition: an acid increases the amount of H+H^+ in water, and a base increases the amount of hydroxide (OHOH^-) in water. A broader definition, which helps explain reactions that don't happen in water, is the Brønsted-Lowry definition. Here, an acid is any molecule that gives away a proton (H+H^+), and a base is any molecule that takes it.

How to Recognize Them

You can often spot an acid because its chemical formula starts with an 'H' (like HClHCl for hydrochloric acid or HNO3HNO_3 for nitric acid). Bases often end in 'OH' (like NaOHNaOH for sodium hydroxide). You can also tell them apart using the pH scale, which goes from 0 to 14. Acids have a pH lower than 7, meaning they have a high concentration of hydrogen ions. Bases have a pH higher than 7, meaning they have a low concentration of hydrogen ions. A pH of exactly 7 is neutral, like pure water.

Where Students Slip Up

A very common mistake is confusing "strong" with "concentrated." A strong acid (like stomach acid) is one where every single molecule donates its proton when put in water. A weak acid (like vinegar) only donates a few of its protons. Concentration, on the other hand, just means how much of the acid you poured into the water. You can have a very dilute strong acid, or a very highly concentrated weak acid!

Worked through

Identify the acid and the base in the following reaction: HCl+NH3Cl+NH4+HCl + NH_3 \rightarrow Cl^- + NH_4^+

Look at what happens to the hydrogen atoms from the left side of the arrow to the right side. The HClHCl starts with one hydrogen and loses it to become ClCl^-. Because it donates a proton, HClHCl is the acid. The NH3NH_3 starts with three hydrogens and gains one to become NH4+NH_4^+. Because it accepts a proton, NH3NH_3 is the base.

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Where this comes from: OpenStax Chemistry 2e, Chapter 14: Acid-Base Equilibria · Khan Academy, AP Chemistry: Acids and bases

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